Palladium-catalyzed asymmetric addition of arylboronic acids to nitrostyrenes

Qun He, Fang Xie, Guanghong Fu, Mao Quan, Chaoren Shen, Guoqiang Yang, Ilya D. Gridnev, Wanbin Zhang

研究成果: Article査読

40 被引用数 (Scopus)

抄録

A palladium-catalyzed asymmetric addition of arylboronic acids to nitrostyrene is reported. The catalytic system employing iPr-IsoQuinox as a chiral ligand in MeOH solvent under an air atmosphere provides the chiral diarylsubstituted products in high yields with good enantioselectivities. A variety of functionalized nitrostyrenes can be used, and the method tolerates some variation in arylboronic acid scope. The stereochemical outcome can be explained using a stereochemical model.

本文言語English
ページ(範囲)2250-2253
ページ数4
ジャーナルOrganic letters
17
9
DOI
出版ステータスPublished - 2015 5月 1

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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