Oximate-bridged trinuclear Dy-Cu-Dy complex behaving as a single-molecule magnet and its mechanistic investigation

Fumihito Mori, Tetsuya Nyui, Takayuki Ishida, Takashi Nogami, Kwang Yong Choi, Hiroyuki Nojiri

研究成果: Article査読

319 被引用数 (Scopus)

抄録

Lanthanide ions are supposed to be promising candidates for the elements of single-molecule magnets (SMMs) because of the large magnetic momentum and anisotropy. We have established the [Dy2Cu] complex as a new SMM. A plausible mechanism for quantum tunneling of magnetization is proposed for the first time among the 4f-3d heterometallic SMMs. The magnetic coupling parameter between Dy and Cu ions was well-defined as -0.155 K.

本文言語English
ページ(範囲)1440-1441
ページ数2
ジャーナルJournal of the American Chemical Society
128
5
DOI
出版ステータスPublished - 2006 2月 8

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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