Oxidation states of GaAs surface and their effects on neutral beam etching during nanopillar fabrication

C. Thomas, Y. Tamura, M. E. Syazwan, A. Higo, S. Samukawa

研究成果: Article査読

17 被引用数 (Scopus)


We have investigated a new process for fabricating GaAs sub-20 nm nanopillars that uses a top-down combination of a bio-template and damage-free neutral beam etching. A two-dimensional array of nanoparticles composed of a protein shell embedded with a metal oxide core was formed on the top of a GaAs surface treated by neutral beam oxidation. Because of device requirements, three low-temperature oxygen techniques were investigated for removing the protein shell prior to the etching process: oxygen radical, oxygen neutral beam, and low-temperature oxygen annealing in vacuum (LT-OAV). X-ray photoelectron spectroscopy was used to monitor the effects of the different treatments on the GaAs surface. While the three processes could efficiently remove a protein shell, subsequent oxidation of the GaAs surface showed some differences in the oxide layer composition. Therefore, LT-OAV was selected considering its lower gallium oxide formation. A hydrogen radical process was then performed at temperatures lower than 400 °C to remove the oxide layer prior to etching. This process completely removed arsenide oxide and only residual gallium oxide was found on the surface afterwards. Etching was performed using a pure chlorine neutral beam of GaAs samples with metal oxide core etching masks. We found that control of the Ga-oxide amount on the surface is the key parameter for controlling the diameter and the density of nanopillars. Finally, high-aspect ratio nanopillars using stacked layers of GaAs and AlGaAs were obtained and showed no damage layer.

ジャーナルJournal of Physics D: Applied Physics
出版ステータスPublished - 2014 5月 30

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学
  • 音響学および超音波学
  • 表面、皮膜および薄膜


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