Outer valence electronic structure of pyrrole studied by electron momentum spectroscopy

Masahiko Takahashi, Ryuji Ogino, Yasuo Udagawa

研究成果: Article査読

23 被引用数 (Scopus)

抄録

The electronic structure of the pyrrole (C4H5N) molecule has been studied using electron momentum spectroscopy at an impact energy of 800 eV plus binding energy. Binding energy spectra have been measured at selected electron momenta. An attempt to clarify the band assignments, which have been in controversy, is made with the aid of theoretical electron momentum profiles calculated using the 6-31++G** basis set. A set of assignments which reproduces the observations is proposed, and it is concluded that electron correlation effects are significant in the innermost π electron ionization.

本文言語English
ページ(範囲)821-827
ページ数7
ジャーナルChemical Physics Letters
288
5-6
DOI
出版ステータスPublished - 1998 5 29

ASJC Scopus subject areas

  • 物理学および天文学(全般)
  • 物理化学および理論化学

フィンガープリント

「Outer valence electronic structure of pyrrole studied by electron momentum spectroscopy」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル