ORIENTATION AND SPECTRAL CHARACTERISTICS OF THE AZOBENZENE CHROMOPHORE IN THE AMMONIUM BILAYER ASSEMBLY.

Masatsugu Shimomura, R. Ando, T. Kunitake

    研究成果: Article査読

    278 被引用数 (Scopus)

    抄録

    Azobenzene-containing, single-chain ammonium amphiphiles in which the alkyl chain length in the tail and spacer portions was systematically varied were prepared, and their aggregation behavior in water was studied by electron microscopy, differential scanning calorimetry and absorption spectroscopy. These amphiphiles exist as molecular dispersions, hydrated microcrystals, micelles, or bilayers. The formation of stable bilayers was deduced on the basis of three criteria which include the spectral agreement between aqueous dispersions and the corresponding cast films. Stable bilayers were obtainable when the sum of tail and spacer is not smaller than C//1//4 to C//1//6, and the tail is at least C//8.

    本文言語English
    ページ(範囲)1134-1143
    ページ数10
    ジャーナルBerichte der Bunsengesellschaft/Physical Chemistry Chemical Physics
    87
    12
    DOI
    出版ステータスPublished - 1983 1 1

    ASJC Scopus subject areas

    • 化学工学(全般)

    フィンガープリント

    「ORIENTATION AND SPECTRAL CHARACTERISTICS OF THE AZOBENZENE CHROMOPHORE IN THE AMMONIUM BILAYER ASSEMBLY.」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

    引用スタイル