Organocatalyst-mediated dehydrogenation of aldehydes to α,β-unsaturated aldehydes, and oxidative and enantioselective reaction of aldehydes and nitromethane catalyzed by diphenylprolinol silyl ether

Yujiro Hayashi, Takahiko Itoh, Hayato Ishikawa

研究成果: Article査読

15 被引用数 (Scopus)

抄録

A one-pot transformation of aldehydes into α,β-unsaturated aldehydes was developed using both N-benzyl-N-methylamine and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) as catalysts and MnO2 as a terminal oxidant. An oxidative and enantioselective reaction of aldehydes and nitromethane was established using both diphenylprolinol silyl ether and DDQ as a catalyst with MnO2 as a terminal oxidant, in which synthetically important β-substituted γ-nitro aldehydes were obtained with excellent enantioselectivity.

本文言語English
ページ(範囲)3661-3669
ページ数9
ジャーナルAdvanced Synthesis and Catalysis
355
18
DOI
出版ステータスPublished - 2013 12 16

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

フィンガープリント 「Organocatalyst-mediated dehydrogenation of aldehydes to α,β-unsaturated aldehydes, and oxidative and enantioselective reaction of aldehydes and nitromethane catalyzed by diphenylprolinol silyl ether」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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