Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene

Yutaka Matsuo, Hiroyuki Isobe, Takatsugu Tanaka, Yasujiro Murata, Michihisa Murata, Koichi Komatsu, Eiichi Nakamura

    研究成果: Article

    50 引用 (Scopus)

    抜粋

    Regioselective multi-addition reaction of organocopper and amine compounds onto dihydrogen-encapsulated [60]fullerene, H2@C60, produced a variety of organic and organometallic derivatives of H2@C60. The X-ray crystallographic analysis of dihydrogen-encapsulated bucky ferrocene, Fe(H2@C60Ph5)C5H5, showed the presence of the dihydrogen molecule located almost in the center but slightly away from the ferrocene moiety. The 1H NMR chemical shift values for the encapsulated molecular hydrogen indicated that these values are susceptible to the magnetic environment of the inside as well as the outside of the fullerene cage.

    元の言語English
    ページ(範囲)17148-17149
    ページ数2
    ジャーナルJournal of the American Chemical Society
    127
    発行部数49
    DOI
    出版物ステータスPublished - 2005 12 14

    ASJC Scopus subject areas

    • Catalysis
    • Chemistry(all)
    • Biochemistry
    • Colloid and Surface Chemistry

    フィンガープリント Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用

    Matsuo, Y., Isobe, H., Tanaka, T., Murata, Y., Murata, M., Komatsu, K., & Nakamura, E. (2005). Organic and organometallic derivatives of dihydrogen-encapsulated [60]fullerene. Journal of the American Chemical Society, 127(49), 17148-17149. https://doi.org/10.1021/ja056077a