TY - JOUR
T1 - Optimal laser control of ultrafast photodissociation of I2 - in water
T2 - Mixed quantum/classical molecular dynamics simulation
AU - Nishiyama, Yoshikazu
AU - Kato, Tsuyoshi
AU - Ohtsuki, Yukiyoshi
AU - Fujimura, Yuichi
PY - 2004/8/8
Y1 - 2004/8/8
N2 - The possibility of controlling the photo-dissociation dynamics of I 2- in water was investigating using a linearized optimal control method. Optimized pulses were designed using an ensemble of photodissociation samples, aiming at the creation of localized dissociation wave packets. Effective optimal pulses, that were designed using a statistically averaged effective dissociation potential, were also introduced. It was found that the effective optimal pulses semiquantitatively reproduced the control achievements calculated by the optimal pulses.
AB - The possibility of controlling the photo-dissociation dynamics of I 2- in water was investigating using a linearized optimal control method. Optimized pulses were designed using an ensemble of photodissociation samples, aiming at the creation of localized dissociation wave packets. Effective optimal pulses, that were designed using a statistically averaged effective dissociation potential, were also introduced. It was found that the effective optimal pulses semiquantitatively reproduced the control achievements calculated by the optimal pulses.
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U2 - 10.1063/1.1771640
DO - 10.1063/1.1771640
M3 - Article
C2 - 15281869
AN - SCOPUS:4344666348
SN - 0021-9606
VL - 121
SP - 2685
EP - 2693
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
IS - 6
ER -