The EPR experiments have been carried out to determine the ligands configurations of the paramagnetic valence anomalies created by UV irradiation in single crystals of [Pt(en) 2 ][Pt(en) 2 C1 2 ](C10 4 ) 4 , en = ethylenediamine. The hyperfine and superhyperfine spectra show that the UV-induced valence anomalies are diraers of the nearest-neighbor Pt nuclei bearing either electron-like or hole-like spin. A variety of their dynamical properties are extracted from the temperature dependence of the quantum yield.
|ジャーナル||Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals|
|出版ステータス||Published - 1992 6 1|
ASJC Scopus subject areas