Optically induced EPR in halogen-bridged linear chain complex [Pt(en) 2 ][Pt(en) 2 Cl 2 ](C10 4 ) 4 , en=NH 2 CH 2 CH 2 NH 2

Noritaka Kuroda, Masamichi Sakai, Masashi Suezawa, Yuichiro Nishina, Koji Sumino, Masahiro Yamashita

研究成果: Article査読

3 被引用数 (Scopus)

抄録

The EPR experiments have been carried out to determine the ligands configurations of the paramagnetic valence anomalies created by UV irradiation in single crystals of [Pt(en) 2 ][Pt(en) 2 C1 2 ](C10 4 ) 4 , en = ethylenediamine. The hyperfine and superhyperfine spectra show that the UV-induced valence anomalies are diraers of the nearest-neighbor Pt nuclei bearing either electron-like or hole-like spin. A variety of their dynamical properties are extracted from the temperature dependence of the quantum yield.

本文言語English
ページ(範囲)169-174
ページ数6
ジャーナルMolecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
216
1
DOI
出版ステータスPublished - 1992 6 1
外部発表はい

ASJC Scopus subject areas

  • 凝縮系物理学

フィンガープリント

「Optically induced EPR in halogen-bridged linear chain complex [Pt(en) <sub>2</sub> ][Pt(en) <sub>2</sub> Cl <sub>2</sub> ](C10 <sub>4</sub> ) <sub>4</sub> , en=NH <sub>2</sub> CH <sub>2</sub> CH <sub>2</sub> NH <sub>2</sub>」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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