One-dimensional single-helix coordination polymer self-assembled by a crown-ether appended-N-heteroacene radical anion

Kyosuke Isoda, Hinako Takahashi, Yuichiro Mutoh, Norihisa Hoshino, Tomoyuki Akutagawa

    研究成果: Article査読

    1 被引用数 (Scopus)

    抄録

    A crown-ether appended N-heteroacene 1 was reduced in the presence of NaBPh4 to the radical anion 2 by accepting one electron transferred from both the cathode and BPh4- as a reductant. The obtained radical anion 2 can function as a radical anion ligand to bridge two sodium ions to self-assemble into one-dimensional helical coordination polymers.

    本文言語English
    ページ(範囲)13125-13129
    ページ数5
    ジャーナルDalton Transactions
    48
    35
    DOI
    出版ステータスPublished - 2019

    ASJC Scopus subject areas

    • 無機化学

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