One-dimensional antiferromagnetic chain in [Ni(dmit)22]- salts of [K+ or Rb+(4,13-diaza-18-crown-6)] supramolecular cation

Nobuhiro Takamatsu, Tomoyuki Akutagawa, Tatsuo Hasegawa, Takayoshi Nakamura, Tamotsu Inabe, Wataru Fujita, Kunio Awaga

研究成果: Article査読

56 被引用数 (Scopus)

抄録

Mixed-stack structures of monovalent [Ni(dmit)2]- and planar M+(4,13-diaza-18-crown-6) (M+ = K+ or Rb+) supramolecular cation were obtained in the isostructural M+(4,13-diaza-18-crown-6)[Ni(dmit)2] salts. The mixed-stack structure decreases the effective π-π overlap of [Ni(dmit)2]- molecules, which results in the one-dimensional Heisenberg antiferromagnetic linear chain of S = 1/2 spins within the crystal.

本文言語English
ページ(範囲)870-871
ページ数2
ジャーナルInorganic Chemistry
39
5
DOI
出版ステータスPublished - 2000 3 6
外部発表はい

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

フィンガープリント 「One-dimensional antiferromagnetic chain in [Ni(dmit)<sub>22</sub>]<sub>-</sub> salts of [K<sup>+</sup> or Rb<sup>+</sup>(4,13-diaza-18-crown-6)] supramolecular cation」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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