Observation of gas molecules adsorbed in the nanochannels of porous coordination polymers by the in situ synchrotron powder diffraction experiment and the MEM/Rietveld charge density analysis

Yoshiki Kubota, Masaki Takata, Tatsuo C. Kobayashi, S. Kitagawa

研究成果: Review article査読

65 被引用数 (Scopus)

抄録

Microporous coordination polymers have attracted attention for their numerous nanotechnology and engineering applications. Nano-coordination space provides some unique properties and functions that could never be realized in conventional porous materials. For the strategy of rational designs and the syntheses of novel porous coordination polymers, the structural information of adsorbed guest molecules inside the nanopores and the host framework is very important. In the present study, we describe the technique of the direct observation of gas molecules adsorbed in the nanochannels of porous coordination polymers by the in situ synchrotron powder diffraction measurement of gas adsorption and the maximum entropy method (MEM)/Rietveld charge density analysis. Specific alignment and properties of molecular oxygen obtained by gas adsorption in the nano-coordination space are revealed.

本文言語English
ページ(範囲)2510-2521
ページ数12
ジャーナルCoordination Chemistry Reviews
251
21-24
DOI
出版ステータスPublished - 2007 11月
外部発表はい

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 無機化学
  • 材料化学

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