Nuclear resonance vibrational spectroscopy and DFT study of peroxo-bridged biferric complexes: Structural insight into peroxo intermediates of binuclear non-heme iron enzymes

Kiyoung Park, Tomohiro Tsugawa, Hideki Furutachi, Yeonju Kwak, Lei V. Liu, Shaun D. Wong, Yoshitaka Yoda, Yasuhiro Kobayashi, Makina Saito, Masayuki Kurokuzu, Makoto Seto, Masatatsu Suzuki, Edward I. Solomon

研究成果: Article査読

8 被引用数 (Scopus)

抄録

Low-frequency vibrational modes of peroxo-bridged high-spin biferric complexes have been observed using nuclear resonance vibrational spectroscopy (NRVS; see picture, PVDOS=partial vibrational density-of-states) and assigned using DFT calculations. Correlations between the spectral features and the structure of peroxo-bridged cores form a basis for structural elucidation of enzyme-peroxo intermediates.

本文言語English
ページ(範囲)1294-1298
ページ数5
ジャーナルAngewandte Chemie - International Edition
52
4
DOI
出版ステータスPublished - 2013 1月 21
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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