Novel method for the fabrication of a charge-transfer complex crystal by photoirradiation

Masaki Matsuda, Miki Nishi, Shoko Koga, Mika Fujishima, Norihisa Hoshino, Tomoyuki Akutagawa, Hiroyuki Hasegawa

    研究成果: Article査読

    4 被引用数 (Scopus)

    抄録

    A novel method for the fabrication of a charge-transfer complex crystal was developed. Photoirradiation of a solution of TPP[Co(tbp)(CN)2] and TPP[Co(Pc)(CN)2] (tbp=tetrabenzoporphyrin, Pc=phthalocyanine, TPP=tetraphenylphosphonium) gave a molecular conducting crystal of a charge-transfer complex TPP[Co(tbp)(CN)2]2, which was produced by the process in which the photoexcited electron in tbp was transferred from the LUMO of tbp to that of Pc. Crystal growth: Photoirradiation of a solution of TPP[Co(tbp)(CN)2] and TPP[Co(Pc)(CN)2] (tbp=tetrabenzoporphyrin, Pc=phthalocyanine, TPP=tetraphenylphosphonium) gave a molecular conducting crystal of a charge-transfer complex TPP[Co(tbp)(CN) 2]2, which was produced by the process in which the photoexcited electron in tbp was transferred from the LUMO of tbp to that of Pc (see figure).

    本文言語English
    ページ(範囲)11318-11321
    ページ数4
    ジャーナルChemistry - A European Journal
    20
    36
    DOI
    出版ステータスPublished - 2014 9月 1

    ASJC Scopus subject areas

    • 触媒
    • 有機化学

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