Novel concepts for organic syntheses based on interfaces and molecular machines

Shinsuke Ishihara, Yutaka Wakayama, Nobuya Hiroshiba, Jonathan P. Hill, Katsuhiko Ariga

研究成果: Article査読

3 被引用数 (Scopus)

抄録

Without doubt, organic chemistry has made significant contributions in improving the qualities of our lives. However, there exists a demand for well-designed molecules of complex structures with additional requirements for low-cost and low-energy production of the materials, which stimulate us to consider innovative concepts in organic synthetic methods. In order to propose innovative methods for next-generation organic synthetic procedures, we present two strategies, (i) organic synthesis within two-dimensional molecular patterns and (ii) organic synthesis driven by molecular machines working at interfaces. For example, synthesis of stereo-regulated polymeric materials in two-dimensional molecular arrays, tip-induced chemical reactions at a solid surface, sequential reactions guided by polymer chains, DNA-nanorobots on two-dimensional DNA origami, ester hydrolysis based on modified behavior of protonated amines at an interface, and several other methods are introduced as pioneering and innovative concepts.

本文言語English
ページ(範囲)428-438
ページ数11
ジャーナルCurrent Organic Synthesis
9
4
DOI
出版ステータスPublished - 2012 8 9

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry

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