Nitrogen-directed ortho-arylation and -heteroarylation of aromatic rings catalyzed by ruthenium complexes

Shuichi Oi, Raito Funayama, Tetsutaro Hattori, Yoshio Inoue

研究成果: Article査読

86 被引用数 (Scopus)

抄録

The ruthenium-catalyzed direct ortho-arylation reactions of 2-phenylpyridine and 2-aryloxazolines have been successfully expanded to the direct aryl-heteroaryl coupling reactions using heteroaryl bromides. The reaction mechanism involving the RuII/RuIV intermediates is proposed from the results of the stoichiometric reaction of a divalent ruthenacycle complex of 2-phenylpyridine with bromobenzene.

本文言語English
ページ(範囲)6051-6059
ページ数9
ジャーナルTetrahedron
64
26
DOI
出版ステータスPublished - 2008 6 23

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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