New morphology-controlled poly(aniline) synthesis using anionic porphyrin aggregate as a template and proton-driven structural changes in the porphyrin aggregate

Tsukasa Hatano, Ah Hyun Bae, Masayuki Takeuchi, Atsushi Ikeda, Seiji Shinkai

研究成果: Article査読

14 被引用数 (Scopus)

抄録

It was found that 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS), which is known to aggregate in a one-dimensional fashion in water, acts as a template for the electropolymerization of aniline on an ITO electrode. Examinations using cyclic voltammetry (CV) and UV-vis spectroscopy established that J-aggregated TPPS molecules are entrapped in the resultant poly(aniline). Scanning electron microscopy (SEM) observations established that poly(aniline) grows to a nanosized rod-like structure, reflecting the aggregation structure of TPPS. The chemical oxidative polymerization of aniline in the presence of TPPS also gave a poly(aniline) rod-like structure containing the TPPS J-aggregate. It was found that the J-aggregation mode in the poly(aniline)/TPPS composite disappears when the medium pH is shifted from acidic to basic, but is regenerated when the medium pH is shifted from basic to acidic. This interconversion could be visually recognized by changes in the color and the fluorescence intensity.

本文言語English
ページ(範囲)1951-1957
ページ数7
ジャーナルBulletin of the Chemical Society of Japan
77
10
DOI
出版ステータスPublished - 2004 10
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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