New fluorimetric alkali and alkaline earth metal cation sensors based on noncyclic crown ethers by means of intramolecular excimer formation of pyrene

Yoshio Suzuki, Tatsuya Morozumi, Hiroshi Nakamura, Masatsugu Shimomura, Takashi Hayashita, Richard A. Bartsh

    研究成果: Article査読

    107 被引用数 (Scopus)

    抄録

    New fluorescent reagents, 2,2′-[oxybis(3-oxapentamethyleneoxy)]-bis[N-(1-pyrenylmethyl)benzamide)] (4) and its analogues (2, 3, and 5) which have two pyrenes at the both terminals of polyoxyethylene compounds, were synthesized, and their complexation behavior with alkaline earth cations was investigated by fluorescence spectrometry, fluorescence lifetimes, and 1H NMR spectrometry. These reagents (3-5) showed strong intramolecular excimer emissions around at 480 nm in the fluorescence spectra. On the complexation with alkaline earth metal cations, the increase of monomer emission around at 400 nm accompanied by the disappearance of intramolecular excimer emission of free reagents was observed. These reagents formed a 1:1 complex, and the order of complex formation constants was Ca2+ ≅ Sr2+ > Ba2+ > Mg2+ > Li+ for all reagents. 1H NMR spectra of these complexes with alkaline earth cations suggested the helical structures of the complexes. Fluorescence spectral changes at the formation of complexes depended on the chain length of the oxyethylene moiety and metal cations. In all cases, the formation of helical structures at the complexation was supported by the 1H NMR spectra.

    本文言語English
    ページ(範囲)7910-7917
    ページ数8
    ジャーナルJournal of Physical Chemistry B
    102
    40
    出版ステータスPublished - 1998 10 1

    ASJC Scopus subject areas

    • 物理化学および理論化学
    • 表面、皮膜および薄膜
    • 材料化学

    フィンガープリント

    「New fluorimetric alkali and alkaline earth metal cation sensors based on noncyclic crown ethers by means of intramolecular excimer formation of pyrene」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

    引用スタイル