NaOH-catalyzed dimerization of monofunctionalized hydrofullerenes: Transition-metal-free, general, and efficient synthesis of single-bonded [60]fullerene dimers

Shirong Lu, Tienan Jin, Ming Bao, Yoshinori Yamamoto

研究成果: Article査読

33 被引用数 (Scopus)

抄録

Unprecedented, transition-metal-free NaOH-catalyzed homo- and cross-dimerizations of monofunctionalized hydrofullerenes are reported. Various single-bonded fullerene dimers were synthesized under mild reaction conditions with remarkably high yields. The use of a NaOH catalyst combined with tetrahydrofuran as a cosolvent under an air atmosphere is critical in achieving highly efficient catalytic dimerization.

本文言語English
ページ(範囲)3466-3469
ページ数4
ジャーナルOrganic letters
14
13
DOI
出版ステータスPublished - 2012 7月 6

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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