Nanoporous copper metal catalyst in click chemistry: Nanoporosity-dependent activity without supports and bases

Tienan Jin, Mei Yan, Menggenbateer, Taketoshi Minato, Ming Bao, Yoshinori Yamamoto

研究成果: Article査読

66 被引用数 (Scopus)

抄録

Nanoporous copper (CuNPore) catalysts with tunable nanoporosity were fabricated from Cu30Mn70 alloy by controlling the de-alloying temperature under free corrosion conditions. The tunable nanoporosity of CuNPore led to a significant enhancement of catalytic activity in click chemistry without using any supports and bases. Characterization of CuNPore surface, high reusability, leaching experiment, and formation of nanostructured copper acetylide revealed that the click reaction occurred at the catalyst surface.

本文言語English
ページ(範囲)3095-3100
ページ数6
ジャーナルAdvanced Synthesis and Catalysis
353
17
DOI
出版ステータスPublished - 2011 11

ASJC Scopus subject areas

  • 触媒
  • 有機化学

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