Nano-polycrystalline diamond synthesized through the decomposition of stearic acid

Hideaki Kawamura, Hiroaki Ohfuji

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Here we report a novel route for synthesizing nano-polycrystalline diamond (NPD) using stearic acid (C18H36O2) as a starting material under high pressure and high temperature. The obtained NPD shows a transparent dark-yellowish color similar to the standard NPD synthesized from graphite and consists of extremely fine diamond grains (∼10 nm). The temperature required for the present synthesis of pure transparent NPD is as low as 1000°C at 13 and 17 GPa, which is surprisingly lower than that for conventional NPD synthesis (1800–2000°C). The amorphous-like, extremely poorly crystalline graphite produced by the thermal decomposition of stearic acid likely provides preferential nucleation sites for diamond and significantly lower the activation energy. The removal of volatile components such as H2O generated through the decomposition from the system is a key to obtain pore-free transparent NPD. Magnesite, MgCO3 and periclase, MgO can be used as an efficient H2O remover through the hydration reaction.

本文言語English
ジャーナルHigh Pressure Research
DOI
出版ステータスAccepted/In press - 2020
外部発表はい

ASJC Scopus subject areas

  • 凝縮系物理学

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