N-heterocyclic carbenes catalyzed umpolung reactions via homoenolates

研究成果: Article査読

2 被引用数 (Scopus)

抄録

Polarity inversion (umpolung or charge affinity inversion) of functional groups is widely recognized as a powerful and efficient synthetic method because it makes possible not only to offer strategic flexibilities but also to form carbon-carbon bonds in the design of complex molecules. Recently, the new approaches of carbonyl synthons employing N-heterocyclic carbene catalyzed homoenolate reactions have been utilized in a variety of applications. In this review, the chemistry highlight in development of the catalytic generation of homoenolates and their application to the novel carbon-carbon bond-forming process is described.

本文言語English
ページ(範囲)1009-1010
ページ数2
ジャーナルYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
65
10
DOI
出版ステータスPublished - 2007 10月
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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