Mono-, di- and trierbium endohedral metallofullerenes: Production, separation, isolation, and spectroscopic study

N. Tagmatarchis, E. Aslanis, K. Prassides, H. Shinohara

研究成果: Article査読

61 被引用数 (Scopus)

抄録

The first successful production and chromatographic isolation of erbium endohedral metallofullerenes are reported. A series of 21 different erbium endohedral metallofullerenes, having one, two, and three erbium metal atoms encapsulated in a range of higher fullerene cages, has been separated and isolated. All these newly synthesized metallofullerenes are characterized by LD-TOF mass spectrometry and UV-vis-NIR absorption spectroscopy. Their possible molecular symmetry, HOMO-LUMO band gap, and electronic structure are discussed in terms of their absorption spectra and high-performance liquid chromatography (HPLC) elution time. Their separation and isolation procedure by multistage HPLC is also discussed in detail.

本文言語English
ページ(範囲)2374-2379
ページ数6
ジャーナルChemistry of Materials
13
7
DOI
出版ステータスPublished - 2001

ASJC Scopus subject areas

  • 化学 (全般)
  • 化学工学(全般)
  • 材料化学

フィンガープリント

「Mono-, di- and trierbium endohedral metallofullerenes: Production, separation, isolation, and spectroscopic study」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル