Molecular dynamics study of gas - Liquid aqueous sodium halide interfaces. II. Analysis of vibrational sum frequency generation spectra

Tatsuya Ishiyama, Akihiro Morita

研究成果: Article査読

75 被引用数 (Scopus)

抄録

The vibrational sum frequency generation (SFG) spectra of gas - liquid interfaces of NaCl and NaI aqueous solutions are computed and analyzed by molecular dynamics (MD) simulations using a flexible and polarizable molecular model. The MD calculations have reproduced the experimental features of SFG spectra, including observed perturbation on the Nal spectra in contrast to little perturbation on NaCl. Analysis of the nonlinear susceptibility revealed that the intermolecular correlation has a significant contribution to the vibrationally resonant amplitude, which largely distorts the generally accepted relationship between the SFG intensity and orientation of individual molecules. In Nal solutions, modest enhancement of ssp intensity in the 3400 cm -1 region is thereby elucidated by this mechanism. Regarding the sps spectra, three spectral components are assigned and elucidated. Calculated remarkable enhancement in the 3400-3800 cm-1 region for NaI solutions is found to be sensitive to the electric double layer structure. It is also revealed that the sps intensity is augmented by the intermolecular water - water correlation effect.

本文言語English
ページ(範囲)738-748
ページ数11
ジャーナルJournal of Physical Chemistry C
111
2
DOI
出版ステータスPublished - 2007 1月 18
外部発表はい

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • エネルギー(全般)
  • 物理化学および理論化学
  • 表面、皮膜および薄膜

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