TY - JOUR
T1 - Mixed conductivity and electrode properties of Mn-doped Bi-Sr-Fe-based perovskite-type oxides
AU - Baek, Doohyun
AU - Kamegawa, Atsunori
AU - Takamura, Hitoshi
PY - 2013/11/11
Y1 - 2013/11/11
N2 - The Fe-site of Bi0.7Sr0.3FeO3 - δ (BSF) was doped with manganese to determine any changes in the charged defects and understand how this change affects the electrode properties of this material. The electrical conductivity and oxygen permeability results suggest that Mn-doping effectively improves the electronic compensation of BSF, which is energetically favored by ionic compensation. In terms of electrode properties, 50 mol% Mn-doped BSF (BSFM55) showed more than one order of magnitude greater electrode resistance than BSF, suggesting that kinetics related to ionic defects plays a more important role than electronic defects in determining the properties of Bi-Sr-Fe based perovskite oxides.
AB - The Fe-site of Bi0.7Sr0.3FeO3 - δ (BSF) was doped with manganese to determine any changes in the charged defects and understand how this change affects the electrode properties of this material. The electrical conductivity and oxygen permeability results suggest that Mn-doping effectively improves the electronic compensation of BSF, which is energetically favored by ionic compensation. In terms of electrode properties, 50 mol% Mn-doped BSF (BSFM55) showed more than one order of magnitude greater electrode resistance than BSF, suggesting that kinetics related to ionic defects plays a more important role than electronic defects in determining the properties of Bi-Sr-Fe based perovskite oxides.
KW - Bi-Sr-Fe-based perovskite-type oxide
KW - Mixed ionic and electronic conductor
KW - Mn-doping effect
KW - Oxygen permeable membrane
KW - SOFC cathode
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U2 - 10.1016/j.ssi.2013.09.056
DO - 10.1016/j.ssi.2013.09.056
M3 - Article
AN - SCOPUS:84887125608
VL - 253
SP - 211
EP - 216
JO - Solid State Ionics
JF - Solid State Ionics
SN - 0167-2738
ER -