Microvoltammetric study of electrochemical hydrogenation of a surface- treated Mg₂Ni alloy single particle

The effects of surface treatments on the hydrogen storage properties of a Mg₂Ni alloy particle were investigated by the microvoltammetric technique, in which a carbon-filament microelectrode was manipulated to make electrical contact with the particle placed in a KOH aqueous solution. It was found that the hydrogen storage properties of Mg₂Ni at room temperature were improved by the surface treatments with a nickel plating solution. The sodium salts (sodium phosphinate and sodium dihydrogen citrate) contained in the nickel plating solution made the alloy form an amorphous-like state, resulting in an improved hydrogen absorption/desorption capacity at room temperature as high as about 150 mA h g^-1 from the original value of 17 mA h g^-1.