Microstructural origin of hysteresis in Ni-Mn-In based magnetocaloric compounds

H. Sepehri-Amin, A. Taubel, T. Ohkubo, K. P. Skokov, O. Gutfleisch, K. Hono

研究成果: Article査読

16 被引用数 (Scopus)

抄録

Microstructures of magnetocaloric Ni-Mn-In-based Heusler alloys, Ni50.2Mn35.0In14.8 and Ni46.1Mn37.9Fe3.0In13.0 were studied to understand the origin of a large difference in thermal hysteresis in these two alloys. In-situ transmission electron microscopy (TEM) observation showed that the Fe containing sample with a large hysteresis shows a discontinuous phase transition due to the existence of nano-scale Fe-rich bcc phase, along with Fe-lean B2 and L21 phases in the austenite state. The Fe-free sample with a low hysteresis shows a uniform phase transition from martensite to austenite initiated by the nucleation of austenite at the twin boundaries. Ni segregation was found at the twin boundaries of the low hysteresis sample that is considered to facilitate the nucleation of the austenite. The phase transition progresses by the growth of the nucleated austenite to the neighboring twins. 5M and 7M modulated martensites in the low hysteresis sample give rise to a slight difference in the phase transition temperatures in the twin bands contributing to the small hysteresis of 4.4 K in the Fe-free sample. Based on these results, we conclude that to minimize the thermal hysteresis of the Ni-Mn-In based magnetocaloric compounds, one of the key factors is to achieve a uniform composition and crystal structure in the alloy.

本文言語English
ページ(範囲)342-349
ページ数8
ジャーナルActa Materialia
147
DOI
出版ステータスPublished - 2018 4 1
外部発表はい

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • セラミックおよび複合材料
  • ポリマーおよびプラスチック
  • 金属および合金

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