Mechanism of suppression of sulfide ion in seawater using steelmaking slag

Akio Hayashi, Satoshi Asaoka, Tetsuya Watanabe, Ryoko Kaneko, Katunori Takahashi, Yasuhito Miyata, Kyunghoi Kim, Tamiji Yamamoto, Ryo Inoue, Tatsuro Ariyama

研究成果: Article査読

7 被引用数 (Scopus)

抄録

In Japan, 15 million tons of steelmaking slag is produced annually as a by-product of the steelmaking process. It is known that steelmaking slag has specific properties to decrease hydrogen sulfide in seawater. To date, however, the specific mechanism is still unknown. This is the first report that explains the process of the slag reducing the hydrogen sulfide level. We added slag to the artificial seawater containing sulfide ion and obtained fine particles. We analyzed the reaction products with X-ray absorption fine structure (XAFS) and scanning electron microscopyenergy dispersive X-ray detector (SEM-EDX) and confirmed corresponding peaks of FeS, FeS2, sulfur and sulfate. We also measured the oxidation-reduction potential (ORP) and found that a shift to oxidizing atmosphere was promoted by adding slag, which oxidized sulfide ion to sulfuric acid ion. These data suggested that hydrogen sulfide level in seawater is reduced not only by the reaction of sulfide with iron contained in steelmaking slag but also by oxidation of sulfide in seawater with steelmaking slag. These results imply that effective utilization of steelmaking slag in coastal areas has a capability to improve the surrounding marine environment.

本文言語English
ページ(範囲)1741-1748
ページ数8
ジャーナルIsij International
54
7
DOI
出版ステータスPublished - 2014
外部発表はい

ASJC Scopus subject areas

  • 材料力学
  • 機械工学
  • 金属および合金
  • 材料化学

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