Mass spectrometric fragmentation of 1-(benzyloxycarbonyl)amino-2-alkyl/ cycloalkyl thioacetates: A thioester pyrolysis-type rearrangement under electron impact ionization

Shu Xu, Jia Xi Xu

    研究成果: Article

    抜粋

    The mass spectrometric fragmentation of 1-(benzyloxycarbonyl)amino-2-alkyl/ cycloalkyl thioacetates has been studied with the aid of mass-analysed ion kinetic energy spectrometry under electron impact ionization. All compounds show a tendency to eliminate a ketene, thioacetic acid, and benzyl carbamate molecule, or an acetyl and benzyloxy radicals. A thioester pyrolysis-type rearrangement under electron impact ionizations was observed.

    元の言語English
    ページ(範囲)1069-1072
    ページ数4
    ジャーナルChinese Chemical Letters
    17
    発行部数8
    出版物ステータスPublished - 2006 8 1

    ASJC Scopus subject areas

    • Chemistry(all)

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