Marine macroalga sargassum horneri as biosorbent for heavy metal removal: Roles of calcium in ion exchange mechanism

B. Southichak, K. Nakano, M. Nomura, N. Chiba, O. Nishimura

研究成果: Article

11 引用 (Scopus)

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Brown seaweed Sargassum horneri, a troublesome biomass scattered along the seashore, was utilized as a biosorbent for Pb(II) removal from aqueous solutions. The Pb(II) adsorption by brown seaweed was enhanced by pretreatment with CaCl2, and the Langmuir adsorption isotherm equation showed a maximum capacity of a Qmax of 0.696 mmol/g and a b value of 94.33 L/mmol. Results obtained from the mass-balance equation derived from the simulation model of the Langmuir adsorption Isotherm suggested that the adsorption performance of brown seaweed biosorbent was sufficient to reduce the concentration of Pb(II) to meet the range of WHO guideline. The mechanism, as elucidated using pH monitoring, adsorption rate and ion exchange model, involved the rapid pH change of metal solutions that led to high reaction rate and Pb(II) uptake in the first 30min of the biosorption process. The energy X-ray analysis's result confirmed the sharp reduction of calcium content in the biosorbent after Pb(II) adsorption. The amount of calcium ions released from the biosorbent was about 1.5 times the amount of Pb(II) adsorbed and proved the role of calcium in the ion exchange mechanism. These adsorption equilibrium and mechanistic studies provide useful information for system design and performance prediction of biosorption processes.

元の言語English
ページ(範囲)697-704
ページ数8
ジャーナルWater Science and Technology
58
発行部数3
DOI
出版物ステータスPublished - 2008 10 6

ASJC Scopus subject areas

  • Environmental Engineering
  • Water Science and Technology

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