Mapping-Out Catalytic Processes in a Metal–Organic Framework with Single-Crystal X-ray Crystallography

Alexandre Burgun, Campbell J. Coghlan, David M. Huang, Wenqian Chen, Satoshi Horike, Susumu Kitagawa, Jason F. Alvino, Gregory F. Metha, Christopher J. Sumby, Christian J. Doonan

研究成果: Article査読

39 被引用数 (Scopus)

抄録

Single-crystal X-ray crystallography is employed to characterize the reaction species of a full catalytic carbonylation cycle within a MnII-based metal–organic framework (MOF) material. The structural insights explain why the Rh metalated MOF is catalytically competent toward the carbonylation of MeBr but only affords stoichiometric turn-over in the case of MeI. This work highlights the capability of MOFs to act as platform materials for studying single-site catalysis in heterogeneous systems.

本文言語English
ページ(範囲)8412-8416
ページ数5
ジャーナルAngewandte Chemie - International Edition
56
29
DOI
出版ステータスPublished - 2017 7 10

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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