Magnetic/conducting bifunctionality due to π/σ-conjugated functional moieties in a stacked ferrimagnetic chain

Hitoshi Miyasaka, Yuichiro Asai, Natsuko Motokawa, Kazuya Kubo, Masahiro Yamashita

研究成果: Article査読

16 被引用数 (Scopus)

抄録

An alternating chain of a paddlewheel [Ru2 II,III(O2CEt)4]+ (EtCO 2- = propionate) complex and [Pt(mnt)2] - (mnt2- = maleonitriledithiolate) has a ferrimagnetic spin arrangement of S = 3/2 and 1/2 local spins, respectively, as well as three-dimensional antiferromagnetic ordering with a canting mode at 8.6 K. This chain is stacked at the [Pt(mnt)2]- units to form a slipped column in the vertical direction against the chain, which acts as a pathway for electrical conduction.

本文言語English
ページ(範囲)9116-9118
ページ数3
ジャーナルInorganic chemistry
49
20
DOI
出版ステータスPublished - 2010 10 18

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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