Magnetic switching by desorption/adsorption of an organic solvent molecule from/on [Ni(dmit) 2 ] 1 salt

Katsuya Ichihashi, Takumi Nishimura, Daisuke Konno, Katsuya Inoue, Toshimi Nakaya, Tomoyuki Akutagawa, Takayoshi Nakamura, Sadafumi Nishihara

研究成果: Article

抜粋

Herein, the synthesis and physical properties of a monovalent [Ni(dmit) 2 ] 1 salt (dmit 21 = 2-thioxo-1,3-dithiole-4,5-dithiolate) containing a supramolecular cation composed of Na + ions, dibenzo[18]crown-6 molecules, and CH 3 CN molecules, has been reported. The desorption/adsorption of CH 3 CN molecules (organic solvent molecules) from/on the [Ni(dmit) 2 ] 1 salt occurred while maintaining the crystalline state and could be utilized to switch the magnetic properties of the salt.

元の言語English
ページ(範囲)329-332
ページ数4
ジャーナルChemistry Letters
48
発行部数4
DOI
出版物ステータスPublished - 2019 1 1

ASJC Scopus subject areas

  • Chemistry(all)

フィンガープリント Magnetic switching by desorption/adsorption of an organic solvent molecule from/on [Ni(dmit) <sub>2</sub> ] <sup>1</sup> salt' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用

    Ichihashi, K., Nishimura, T., Konno, D., Inoue, K., Nakaya, T., Akutagawa, T., Nakamura, T., & Nishihara, S. (2019). Magnetic switching by desorption/adsorption of an organic solvent molecule from/on [Ni(dmit) 2 ] 1 salt Chemistry Letters, 48(4), 329-332. https://doi.org/10.1246/cl.181031