Magnetic properties of the UCo1-xTxAl solid solutions (T=Rh and Ir)

A. V. Andreev, I. K. Kozlovskaya, N. V. Mushnikov, T. Goto, V. Sechovský, Y. Homma, Y. Shiokawa

研究成果: Article

18 引用 (Scopus)


Results of crystal-structure and magnetic studies of solid solutions between a 5f-band metamagnet UCoAl and ferromagnets URhAl and UIrAl are reported. The UCo1-xRhxAl system exhibits a continuous solubility with a monotonous dependence of lattice parameters. For the UCo1-xIrxAl compounds we observe this behaviour only for concentrations close to parent compounds, i.e. at x≤0.2 and x≥0.8, leaving the alloys with intermediate concentrations structurally heterogeneous. In the common solubility region lattice parameters in both systems are nearly identical. Also in magnetism, Rh and Ir substitutions for Co yield analogous effects. Ferromagnetism is stabilised for x>0.1 and the Curie temperature and the spontaneous moment exhibits qualitatively similar concentration dependence. These results imply similar evolution of electronic structure involving variations of the 5f-ligand hybridization due to Rh and Ir substitutions.

ジャーナルJournal of Alloys and Compounds
出版物ステータスPublished - 1999 1 1

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

フィンガープリント Magnetic properties of the UCo<sub>1-x</sub>T<sub>x</sub>Al solid solutions (T=Rh and Ir)' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用

    Andreev, A. V., Kozlovskaya, I. K., Mushnikov, N. V., Goto, T., Sechovský, V., Homma, Y., & Shiokawa, Y. (1999). Magnetic properties of the UCo1-xTxAl solid solutions (T=Rh and Ir). Journal of Alloys and Compounds, 284(1-2), 77-81.