Magnetic anisotropy and molecular assembling in d complex cation-f complex anion type coordination compounds

Marilena Ferbinteanu, Fanica Cimpoesu, Takashi Kajiwara, Masahiro Yamashita

研究成果: Article査読

10 被引用数 (Scopus)

抄録

The system [Fe(bpca)2][Er(NO3)4(H2O)2] (1) (Hbpca = bis(2-pyridil-carbonyl) amine) is a complex cation-complex anion type coordination compound consisting of distinct d and f units, interlinked by hydrogen bonds. Particularly, the association of f-type complex anions in dimers is remarked and discussed. The energy decomposition analyses based on DFT calculations offered supplementary insight into the coordination effects at the lanthanide ions and the hydrogen bond driven supramolecular association of the complex units. Special ab initio procedures and subsequent modeling afforded the computation of anisotropic magnetization tensors of the [Er(NO3)4(H2O)2]- f-type units. The computed results are in line with the experimental data for compound 1.

本文言語English
ページ(範囲)760-765
ページ数6
ジャーナルSolid State Sciences
11
4
DOI
出版ステータスPublished - 2009 4月

ASJC Scopus subject areas

  • 化学 (全般)
  • 材料科学(全般)
  • 凝縮系物理学

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