Mössbauer study of Fe-base amorphous ultrafine particles prepared by chemical reduction

J. Saida, M. Ghafari, Y. Nakamura, A. Inoue, T. Masumoto

研究成果: Article査読

5 被引用数 (Scopus)

抄録

Mössbauer spectroscopy was applied for the structure analysis of chemically synthesized FeB and FeM-B (M = Co, Ni) particles using KBH4as a reducing agent. The structure of FeB particles depends on the mixing molar ratio of KBH4to Fe2+ ions,Mr. The particles consist of amorphous FeB alloys and Fe3+oxides for MR≥ 10.0, while amorphous FeB alloys, Fe3+ oxides and the α-phase for MR < 10.0. The distribution of magnetic hyperfine field P(Bhf) also changes with MR. The average value of Bhfchanges discontinuously around MR = 10.0. The substitution of Fe by Ni atoms has a drastic effect on the Mössbauer parameters, indicating the change of the hyperfine field.

本文言語English
ページ(範囲)223-224
ページ数2
ジャーナルNuclear Inst. and Methods in Physics Research, B
76
1-4
DOI
出版ステータスPublished - 1993 4 4
外部発表はい

ASJC Scopus subject areas

  • Nuclear and High Energy Physics
  • Instrumentation

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