Luminescence and scintillation properties of Mg-codoped LuAG:Pr single crystals annealed in air

Jan Pejchal, Maksym Buryi, Vladimir Babin, Petr Prusa, Alena Beitlerova, Jan Barta, Lubomir Havlak, Kei Kamada, Akira Yoshikawa, Valentin Laguta, Martin Nikl

研究成果: Article査読

26 被引用数 (Scopus)

抄録

The influence of the Mg2+ codoping and annealing in the air on the scintillation and luminescence characteristics of Pr-doped lutetium-aluminum garnet crystals (LuAG) was studied to find a possible positive effect of Pr4+. The overall scintillation efficiency under X-ray excitation of the annealed Pr- doped samples decreased with increasing Mg concentration. This was explained by increased overlap of the Pr3+ 5d-4f emission with the charge-transfer (CT) absorption band of the Pr4+ ion stabilized by Mg2+. This absorption caused even greater decrease of the light yield, as the light is collected from the whole sample volume in the pulse-height spectrum measurement. Electron centers based on oxygen vacancies (F+ centers) which can have negative influence on scintillation mechanism were revealed by the electron paramagnetic resonance (EPR) experiments. The O- hole center was detected as well and the temperature dependences of the EPR spectra showed that its thermal stability was decreased by Mg codoping. Negligible changes in the decay time of Pr3+ 5d-4f photoluminescence exclude the non-radiative energy transfer from relaxed 5d1 excited state of Pr3+ towards CT absorption transition of Pr4+ and suggest that simple reabsorption of the emitted light takes place. Unlike for the Ce-doped analogs, promoting the Pr3+ luminescence center to the tetravalent state by divalent ion co-doping and air annealing did not improve scintillation properties of Pr-doped LuAG.

本文言語English
ページ(範囲)277-285
ページ数9
ジャーナルJournal of Luminescence
181
DOI
出版ステータスPublished - 2017 1 1

ASJC Scopus subject areas

  • 生物理学
  • 生化学
  • 化学 (全般)
  • 原子分子物理学および光学
  • 凝縮系物理学

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