Low-valent iron-catalyzed C-C bond formation-addition, substitution, and C-H bond activation

Eiichi Nakamura, Naohiko Yoshikai

研究成果: Article査読

405 被引用数 (Scopus)

抄録

Figure presented. The use of iron as a catalyst for organic synthesis has been increasingly attracting the interest of chemists from economical and ecological points of view. While Fe(III) and Fe(II) catalysts have long been used as Lewis acids for synthesis, we have been interested in exploration of catalysis based on rather unexplored organoiron chemistry since the late 1990s. This Perspective summarizes a series of iron-catalyzed C-C bond formation reactions developed by us, which include (asymmetric) carbometalation of olefins, cross-coupling of alkyl halides, and activation of sp2 and sp3 C-H bonds.

本文言語English
ページ(範囲)6061-6067
ページ数7
ジャーナルJournal of Organic Chemistry
75
18
DOI
出版ステータスPublished - 2010 9 17
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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