Long range influence of an excess proton on the architecture of the hydrogen bond network in large-sized water clusters

Kenta Mizuse, Asuka Fujii, Naohiko Mikami

研究成果: Article査読

39 被引用数 (Scopus)

抄録

Infrared spectra of completely size-selected protonated water clusters H+ (H2 O)n are reported for clusters ranging from n=15 to 100. The behavior of the dangling OH stretch bands shows that the hydrogen bond structure in H+ (H2 O)n is uniquely different to that of (H2 O)n up to the size of n=100, at least. This finding indicates that the presence of an excess proton creates a characteristic morphology in the hydrogen bond network architecture of more than 100 surrounding water molecules.

本文言語English
論文番号231101
ジャーナルJournal of Chemical Physics
126
23
DOI
出版ステータスPublished - 2007 8 2

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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