抄録
Phenylene-thiophene-based liquid crystalline π-conjugated copolymers bearing mesogenic groups as side chains were synthesized via a Stille polycondensation reaction and confirmed to exhibit a nematic liquid crystal phase at appropriate temperatures. The formation of a nematic phase, but not a smectic phase indicates cooperation of the main chain and side chain in the formation of a nematic main-chain/side-chain liquid crystal phase. The generation of polarons in the main chain as charge carriers during in-situ vapor doping of iodine is confirmed to increase with a doping progresses, exhibiting Dysonian paramagnetic behavior typical of conductive polymers.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 22-37 |
| ページ数 | 16 |
| ジャーナル | Materials |
| 巻 | 2 |
| 号 | 1 |
| DOI | |
| 出版ステータス | Published - 2009 |
| 外部発表 | はい |
ASJC Scopus subject areas
- Materials Science(all)