Layered ferrimagnets constructed from charge-transferred paddlewheel [Ru2] units and TCNQ derivatives: The importance of interlayer translational distance in determining magnetic ground state

研究成果: Article査読

6 被引用数 (Scopus)

抄録

A donor (D)/acceptor (A) assembly reaction using the paddlewheel-type diruthenium(ii,ii) complex [Ru2(3,5-F2PhCO2)4(THF)2] (3,5-F2PhCO2 - = 3,5-difluorobenzoate; abbreviated hereafter as [Ru2]) as D and 7,7,8,8-tetracyano-p-quinodimethane derivatives (TCNQRx; 2,5-R-substituted TCNQ) as A in a DCM/TCE or DCE solvent system (DCM = dichloromethane, TCE = 1,1,2,2-tetrachloroethane, DCE = 1,2-dichloroethane) led to the formation of D2A-type two-dimensional layered compounds [{Ru2(3,5-F2PhCO2)4}2{TCNQRx}]·nsolv (Rx = H2 (1), Rx = Me2, (2), and Rx = (OEt)2 (3)). All the compounds had similar two-dimensional fishnet-type structures, where the two [Ru2] units were fully coordinated with the four cyano groups of TCNQRx. The compounds 1-3 were categorized as a one-electron transferred ionic state (1e-I) with D+-A--D formulation (D+[RuII,III2]+; A-TCNQRx -). This subunit state formally derived a ferrimagnetically ordered state composed of up-spins with S = 1 for [RuII,II2] and S = 3/2 for [RuII,III2]+ and a down-spin of S = 1/2 for TCNQRx -, with antiferromagnetic superexchange interactions in each layer. Eventually, 1-3 became three-dimensional ferrimagnets with Curie temperatures TC = 93, 93, and 92 K, respectively, owing to the presence of interlayer ferromagnetic interactions. The interlayer translational distances (l2) for the three compounds were 10.56, 10.54, and 10.84 Å, respectively, which agreed with the empirical prediction based on the threshold value of l2 > 10.3 Å for a valid ferromagnetic interaction.

本文言語English
ページ(範囲)11760-11768
ページ数9
ジャーナルDalton Transactions
47
34
DOI
出版ステータスPublished - 2018

ASJC Scopus subject areas

  • Inorganic Chemistry

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