Kinetics of formation and coarsening of nanoporous α-titanium dealloyed with Mg melt

Masashi Tsuda, Takeshi Wada, Hidemi Kato

研究成果: Article査読

43 被引用数 (Scopus)

抄録

The transition behavior from a Ti-Cu alloy to nanoporous α-Ti, the kinetics of the dealloying reaction, and the coarsening of nanoporous α-Ti were studied, and the mechanism of dealloying with a metallic melt was investigated. When a Ti50Cu50 alloy disk was immersed in a Mg melt, the Cu content decreased from the surface of the disk, and transition layers of α-Ti and Ti2Cu were formed. The growth of the transition layers followed a parabolic law and the activation energy was close to those reported for the diffusion of solute atoms in liquids, suggesting that diffusion of Cu in the Mg melt mainly contributed to the rate-controlling process for the dealloying reaction. The temperature and time dependences of the ligament size followed a power law with an exponent of 4, suggesting that surface diffusion plays an important role in coarsening. All of these results are consistent with those reported for dealloying in aqueous solution, indicating that the underlying dealloying mechanism in a metallic melt is similar to that in aqueous solution.

本文言語English
論文番号113503
ジャーナルJournal of Applied Physics
114
11
DOI
出版ステータスPublished - 2013 9月 21

ASJC Scopus subject areas

  • 物理学および天文学(全般)

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