Kinetic gate-opening process in a flexible porous coordination polymer

Daisuke Tanaka, Keiji Nakagawa, Masakazu Higuchi, Satoshi Horike, Yoshiki Kubota, Tatsuo C. Kobayashi, Masaki Takata, Susumu Kitagawa

研究成果: Article査読

257 被引用数 (Scopus)

抄録

(Graph Presented) Open the gate! A porous coordination polymer shows abrupt changes in its adsorption isotherm with guest-dependent gate-opening pressure (see picture). Kinetic analysis reveals that adsorption with structure transformation follows a gate-opening model, in which adsorption proceeds through the formation of an intermediate by a gate-opening process. This process provides a significant difference in onset pressure between similar gas molecules.

本文言語English
ページ(範囲)3914-3918
ページ数5
ジャーナルAngewandte Chemie - International Edition
47
21
DOI
出版ステータスPublished - 2008 5 13
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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