抄録
A kinetic study of the thermal irreversible isomerization of an isolable dialkylsilylene into the corresponding cyclic silene revealed that the activation enthalpy (ΔH‡) and entropy (ΔS ‡) are 18.49 ± 0.43 kcal mol-1 and -20.32 ± 1.35 cal mol-1 K-1, respectively. The relatively low ΔH‡ and negative ΔS‡ values are in accord with the concerted 1,2-silyl migration via a cyclic transition state as previously proposed. The cyclic silene in benzene-d6 isomerized photochemically into the corresponding alkenylsilane via 1,3-hydrogen shift.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 919-921 |
| ページ数 | 3 |
| ジャーナル | Organometallics |
| 巻 | 28 |
| 号 | 3 |
| DOI | |
| 出版ステータス | Published - 2009 2月 9 |
ASJC Scopus subject areas
- 物理化学および理論化学
- 有機化学
- 無機化学