Iron-Catalyzed Directed C−H Silylation of Pivalophenone N−H Imines

Wengang Xu, Jie Hui Pek, Naohiko Yoshikai

研究成果: Article査読

9 被引用数 (Scopus)

抄録

An iron-catalyzed, N−H imine-directed arene C−H silylation reaction with hydrosilane has been achieved. Pivalophenone N−H imine undergoes ortho C−H silylation with triethylsilane in the presence of [Fe3(CO)12] as a catalyst and norbornene as a hydrogen acceptor. The product can be readily transformed into ortho-silylated benzonitrile via conversion of the imine functionality to a cyano group under peroxide photolysis.

本文言語English
ページ(範囲)1351-1354
ページ数4
ジャーナルAsian Journal of Organic Chemistry
7
7
DOI
出版ステータスPublished - 2018 7
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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