Iron-catalyzed direct arylation through directed C-H bond activation

Jakob Norinder, Arimasa Matsumoto, Naohiko Yoshikai, Eiichi Nakamura

研究成果: Article査読

329 被引用数 (Scopus)

抄録

An iron-catalyzed C-C bond formation reaction of a nitrogen-containing aromatic compound with an arylzinc reagent takes place at 0 °C in a good to quantitative yield. The reaction involves a C-H bond activation directed by a neighboring nitrogen atom. The important additives in this reaction are 1,10-phenanthroline, tetramethylethylenediamine, and 1,2-dichloro-2-methylpropane, in the absence of which a very low product yield was observed.

本文言語English
ページ(範囲)5858-5859
ページ数2
ジャーナルJournal of the American Chemical Society
130
18
DOI
出版ステータスPublished - 2008 5月 7
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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