Ionic liquid-mediated epitaxy of high-quality C 60 crystallites in a vacuum

Yoko Takeyama, Shingo Maruyama, Hiroki Taniguchi, Mitsuru Itoh, Keiji Ueno, Yuji Matsumoto

研究成果: Article査読

19 被引用数 (Scopus)

抄録

Ionic liquid-mediated vacuum deposition was demonstrated as a novel growth technique for high-quality C 60 crystallites. In this process the ionic liquid worked as a solvent, i.e. the gas phase C 60 precursors were continuously fed into the ionic liquid on a substrate in a vacuum chamber, from which the nucleation and the subsequent growth of C 60 crystallites proceeded. The impact of varying the substrate on the growth behaviour was intensively examined in terms of not only the lattice-mismatch between C 60 and the substrates, but also the wetting behavior of the ionic liquid on the substrates. This led to a significant improvement of the C 60 crystallinity and epitaxial growth was successfully found on certain substrates. In particular, molecularly smooth and thick C 60 hexagonal-shaped crystallites epitaxially grew on a MoS 2 substrate, the average size of which reached as large as 10 μm.

本文言語English
ページ(範囲)4939-4945
ページ数7
ジャーナルCrystEngComm
14
15
DOI
出版ステータスPublished - 2012 8 7
外部発表はい

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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