Inversion of the Axial Information during Oxidative Aromatization in the Synthesis of Axially Chiral Biaryls with Organocatalysis as a Key Step

Seitaro Koshino, Akira Takikawa, Keiichi Ishida, Tohru Taniguchi, Kenji Monde, Eunsang Kwon, Shigenobu Umemiya, Yujiro Hayashi

研究成果: Article査読

3 被引用数 (Scopus)

抄録

The pot-economical, highly enantioselective synthesis of axially chiral biaryls was developed by using one-pot organocatalyst-mediated domino and aromatization reactions as key steps. The axial information of the precursor, which also has central chirality, was completely inverted in the final biaryls. The inversion of the axial information occurred in the conversion of the central chirality to the axial chirality of an oxidative aromatization step.

本文言語English
ページ(範囲)4524-4530
ページ数7
ジャーナルChemistry (Weinheim an der Bergstrasse, Germany)
26
20
DOI
出版ステータスPublished - 2020 4 6

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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