Internally 1,4-phenylene-bridged meso aryl-substituted expanded porphyrins: The decaphyrin and octaphyrin cases

Venkataramanarao G. Anand, Shohei Saito, Soji Shimizu, Atsuhiro Osuka

研究成果: Article査読

64 被引用数 (Scopus)

抄録

Current affairs: Incorporation of a 1,4-phenylene bridge into meso aryl-substituted decaphyrin and octaphyrin has a profound impact on the structural and electronic properties of the macrocycles. Bridged decaphyrin has two oxidation states, one of which shows a rather strong diatropic ring current. X-ray crystal structure analyses reveal bridged octaphyrin possesses a p-quinodimethane unit, while bridged decaphyrin has a phenylene unit (see picture). (Chemical Equation Presented).

本文言語English
ページ(範囲)7244-7248
ページ数5
ジャーナルAngewandte Chemie - International Edition
44
44
DOI
出版ステータスPublished - 2005 11月 11

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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