Internal amide-triggered cycloaromatization of maduropeptin-like nine-membered enediyne

Yutaro Norizuki, Kazuo Komano, Itaru Sato, Masahiro Hirama

研究成果: Article査読

8 被引用数 (Scopus)

抄録

In the Masamune-Bergman cyclization of a nine-membered non-conjugated enediyne with an internal, maduropeptin-like nucleophile, the exocyclic alkene migrated to form the nine-membered conjugated enediyne, triggered by the intramolecular addition of the amide group; final aromatized products showed up to 85% yield.

本文言語English
ページ(範囲)5372-5374
ページ数3
ジャーナルChemical Communications
42
DOI
出版ステータスPublished - 2008 11 10

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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